Отправить статью по E-mail Synthesis and Structure of Bis(Ethylenediamine-N,N-Di-3-Propionato)Zinc Dihydrate
- Авторы: Tsirul’nikova N.V.1, Dernovaya E.S.1, Volosneva O.N.2, Ananyev I.V.3, Belus S.K.1
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Учреждения:
- The Federal State Unitary Enterprise “Institute of Chemical Reagents and High Purity Chemical Substances of National Research Centre “Kurchatov Institute”
- Federal Research and Clinical Center of Physicochemical Medicine
- Nesmeyanov Institute of Organoelement Compounds
- Выпуск: Том 63, № 10 (2018)
- Страницы: 1322-1325
- Раздел: Coordination Compounds
- URL: https://journals.rcsi.science/0036-0236/article/view/169035
- DOI: https://doi.org/10.1134/S0036023618100194
- ID: 169035
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Аннотация
Bis(ethylenediamine-N,N-di-3-propionato)zinc dihydrate [Zn(EDDP)]2 ∙ 2H2O is prepared from dichloro(ethylenediamine-N,N-di-3-propionato)zinc in the presence of silver(I) oxide. The prepared complex is studied by X-ray diffraction and spectroscopic methods. A molecule of the complex has a centrosymmetric dimeric structure. Zn atoms have trigonal-bipyramidal coordination formed by the nitrogen atoms of primary and tertiary amino groups, two oxygen atoms of propionic groups of one EDDP molecule, and one oxygen atom of the other.
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N. Tsirul’nikova
The Federal State Unitary Enterprise “Institute of Chemical Reagents and High Purity Chemical Substances of National Research Centre “Kurchatov Institute”
Автор, ответственный за переписку.
Email: nv.tsir@mail.ru
Россия, Moscow, 107076
E. Dernovaya
The Federal State Unitary Enterprise “Institute of Chemical Reagents and High Purity Chemical Substances of National Research Centre “Kurchatov Institute”
Email: nv.tsir@mail.ru
Россия, Moscow, 107076
O. Volosneva
Federal Research and Clinical Center of Physicochemical Medicine
Email: nv.tsir@mail.ru
Россия, Moscow, 119435
I. Ananyev
Nesmeyanov Institute of Organoelement Compounds
Email: nv.tsir@mail.ru
Россия, Moscow, 119991
S. Belus
The Federal State Unitary Enterprise “Institute of Chemical Reagents and High Purity Chemical Substances of National Research Centre “Kurchatov Institute”
Email: nv.tsir@mail.ru
Россия, Moscow, 107076
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