μ2-Oxobis[(aroxo)tris(para-tolyl)antimony]: Synthesis and Structure
- Авторы: Sharutin V.V.1, Sharutina O.K.1, Efremov A.N.1
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Учреждения:
- National South Ural State Research University
- Выпуск: Том 63, № 3 (2018)
- Страницы: 343-348
- Раздел: Coordination Compounds
- URL: https://journals.rcsi.science/0036-0236/article/view/168508
- DOI: https://doi.org/10.1134/S0036023618030208
- ID: 168508
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Аннотация
µ2-Oxobis[(2,4,6-tribromophenoxo)tris(para-tolyl)antimony] (I), µ2-oxobis[(2,3,4,5,6-pentachlorophenoxo) tris(para-tolyl)antimony] (II), and µ2-oxobis(2,4-dinitrophenoxo)tris(para-tolyl)antimony] (III) have been synthesized with high yields by the reaction of tris(para-tolyl)antimony with 2,4,6-tribromo-, 2,3,4,5,6-pentachloro-, and 2,4-dinitrophenol, respectively, in ether in the presence of tert-butylhydroperoxide. The Sb atoms in complexes I, II, and III have a distorted trigonal bipyramidal coordination with the aroxyl ligands and the bridging oxygen atom in axial positions. The central Sb–O–Sb moiety in molecules of complexes I–III has an angular structure.
Об авторах
V. Sharutin
National South Ural State Research University
Автор, ответственный за переписку.
Email: vvsharutin@rambler.ru
Россия, Chelyabinsk, 454080
O. Sharutina
National South Ural State Research University
Email: vvsharutin@rambler.ru
Россия, Chelyabinsk, 454080
A. Efremov
National South Ural State Research University
Email: vvsharutin@rambler.ru
Россия, Chelyabinsk, 454080
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