Synthesis and X-ray Crystallographic Study of [(UO2)2(C3H2O4)(Cl)2(C4H9NO)4]


Citar

Texto integral

Acesso aberto Acesso aberto
Acesso é fechado Acesso está concedido
Acesso é fechado Somente assinantes

Resumo

Crystals of [(UO2)2(mal)(Cl)2(DMA)4] (mal2– is malonate ion and DMA is dimethylacetamide) have been synthesized and studied by X-ray crystallography. The key structure units are binuclear island complexes [(UO2)2(mal)(Cl)2(DMA)4], which belong to the A2Q02M61 crystal-chemical group (A = UO22+, Q02 = mal2–, M1 = Cl and DMA) of uranyl complexes. The complexes form a framework through a system of intermolecular nonbonded interactions, which are characterized by means of the Voronoi–Direchlet molecular polyhedron method.

Sobre autores

Ya. Medvedkov

Samara National Research University Named after Academician S.P. Korolev

Email: lserezh@samsu.ru
Rússia, Samara, 443086

M. Grigor’ev

Frumkin Institute of Physical Chemistry and Electrochemistry

Email: lserezh@samsu.ru
Rússia, Moscow, 119071

L. Serezhkina

Samara National Research University Named after Academician S.P. Korolev

Autor responsável pela correspondência
Email: lserezh@samsu.ru
Rússia, Samara, 443086

D. Pushkin

Samara National Research University Named after Academician S.P. Korolev

Email: lserezh@samsu.ru
Rússia, Samara, 443086

V. Serezhkin

Samara National Research University Named after Academician S.P. Korolev

Email: lserezh@samsu.ru
Rússia, Samara, 443086

Arquivos suplementares

Arquivos suplementares
Ação
1. JATS XML

Declaração de direitos autorais © Pleiades Publishing, Ltd., 2018