Отправить статью по E-mail Synthesis of Boron-Containing Siloxanes by Reaction of Hydroxy-closo-Decaborates with Dihalosilanes
- Авторы: Klyukin I.N.1, Zhdanov A.P.1, Bykov A.Y.1, Retivov V.M.2, Zhizhin K.Y.1, Kuznetsov N.T.1
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Учреждения:
- Kurnakov Institute of General and Inorganic Chemistry
- Research Institute of Highly Pure Chemical Substances and Chemicals
- Выпуск: Том 63, № 2 (2018)
- Страницы: 213-218
- Раздел: Physical Methods of Investigation
- URL: https://journals.rcsi.science/0036-0236/article/view/168422
- DOI: https://doi.org/10.1134/S0036023618020110
- ID: 168422
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Аннотация
A new approach to the preparation of boron-containing siloxanes based on cluster boron anions has been suggested. This approach consists in the reaction of hydroxy derivatives of closo-decaborate anion [B10H10–n(OH)n]2– (n = 1, 2) with dihalosilanes SiR2Cl2 (R = CH3, t-C4H9, C6H5). The obtained compounds have been characterized by IR, ESI/MS, and NMR (1H, 11B, 13C) spectroscopy.
Об авторах
I. Klyukin
Kurnakov Institute of General and Inorganic Chemistry
Автор, ответственный за переписку.
Email: klukinil@gmail.com
Россия, Moscow, 119991
A. Zhdanov
Kurnakov Institute of General and Inorganic Chemistry
Email: klukinil@gmail.com
Россия, Moscow, 119991
A. Bykov
Kurnakov Institute of General and Inorganic Chemistry
Email: klukinil@gmail.com
Россия, Moscow, 119991
V. Retivov
Research Institute of Highly Pure Chemical Substances and Chemicals
Email: klukinil@gmail.com
Россия, Moscow, 107076
K. Zhizhin
Kurnakov Institute of General and Inorganic Chemistry
Email: klukinil@gmail.com
Россия, Moscow, 119991
N. Kuznetsov
Kurnakov Institute of General and Inorganic Chemistry
Email: klukinil@gmail.com
Россия, Moscow, 119991
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