Copper(II) coordination compounds with 2-(7-bromo-2-oxo-5-phenyl-3 H -1,4-benzdiazepin-1-yl)acetohydrazide and products of its condensation with pyruvic acid

A. V. Pulya; I. I. Seifullina; L. S. Skorokhod; N. N. Efimov; E. A. Ugolkova; V. V. Minin

doi:10.1134/S0036023616010204

Copper(II) coordination compounds with 2-(7-bromo-2-oxo-5-phenyl-3H-1,4-benzdiazepin-1-yl)acetohydrazide and products of its condensation with pyruvic acid

Авторы: Pulya A.V.¹, Seifullina I.I.¹, Skorokhod L.S.¹, Efimov N.N.², Ugolkova E.A.², Minin V.V.²
Учреждения:
1. Mechnikov National University
2. Kurnakov Institute of General and Inorganic Chemistry
Выпуск: Том 61, № 1 (2016)
Страницы: 38-42
Раздел: Coordination Compounds
URL: https://journals.rcsi.science/0036-0236/article/view/167042
DOI: https://doi.org/10.1134/S0036023616010204
ID: 167042

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Some methods for the synthesis of copper(II) complexes with 2-(7-bromo-2-oxo-5-phenyl-3H-1,4-benzodiazepin-1-yl)acetohydrazide (Hydr) ([Cu(Hydr)(H₂O)Cl₂]) and products of its condensation with pyruvic acid ([Cu(HydrHPv)(H₂O)Cl₂] and, with alkalization to pH 8, [Cu(HydrPv)₂]) were developed, and the complexes themselves were synthesized. The complexes were characterized by electrical conductivity, magnetic susceptibility, and IR and EPR spectroscopy measurements.