[Co(solv)6][B10H10] (solv = DMF and DMSO) for low-temperature synthesis of borides
- Autores: Avdeeva V.V.1, Polyakova I.N.1, Vologzhanina A.V.2, Goeva L.V.1, Buzanov G.A.1, Generalova N.B.1, Malinina E.A.1, Zhizhin K.Y.1, Kuznetsov N.T.1
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Afiliações:
- Kurnakov Institute of General and Inorganic Chemistry
- Nesmeyanov Institute of Organoelement Compounds
- Edição: Volume 61, Nº 9 (2016)
- Páginas: 1125-1134
- Seção: Physical Methods of Investigation
- URL: https://journals.rcsi.science/0036-0236/article/view/166752
- DOI: https://doi.org/10.1134/S0036023616090023
- ID: 166752
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Resumo
The synthesis and structure of complexes [Co(solv)6][B10H10] (solv = DMF and DMSO) have been reported. Both complexes have been prepared in a high yield by the reaction between cobalt(II) salts and closo-decaborates Cat2[B10H10] in the corresponding solvent. The complexes have been characterized by elemental analysis, IR and UV spectroscopy, X-ray powder diffraction, and X-ray crystallography. The thermal properties of the compounds have been studied in the temperature range 20–600°C under argon. The conditions to form cobalt borides have been determined based on the results of thermal analysis, subsequent annealing of the complexes in various conditions, and analysis of IR spectra of the resulting thermolysis products.
Sobre autores
V. Avdeeva
Kurnakov Institute of General and Inorganic Chemistry
Autor responsável pela correspondência
Email: avdeeva.varvara@mail.ru
Rússia, Leninskii pr. 31, Moscow, 119991
I. Polyakova
Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Rússia, Leninskii pr. 31, Moscow, 119991
A. Vologzhanina
Nesmeyanov Institute of Organoelement Compounds
Email: avdeeva.varvara@mail.ru
Rússia, ul. Vavilova 28, Moscow, 119991
L. Goeva
Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Rússia, Leninskii pr. 31, Moscow, 119991
G. Buzanov
Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Rússia, Leninskii pr. 31, Moscow, 119991
N. Generalova
Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Rússia, Leninskii pr. 31, Moscow, 119991
E. Malinina
Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Rússia, Leninskii pr. 31, Moscow, 119991
K. Zhizhin
Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Rússia, Leninskii pr. 31, Moscow, 119991
N. Kuznetsov
Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Rússia, Leninskii pr. 31, Moscow, 119991
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