Synthesis and Investigation of Thermodynamic Properties of Cu5V2O10


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Cu5V2O10 is prepared by solid-phase synthesis via sequential air calcination of a stoichiometric CuO-V2O5 mixture. Its high-temperature heat capacity is measured by differential scanning calorimetry. The thermodynamic properties (enthalpy and entropy changes and scaled Gibbs free energy) are calculated using the experimental dependence Cp =f(T). It is shown that specific heat capacity correlates with the composition of oxides in the CuO−V2O5 system.

Sobre autores

N. Galiakhmetova

Institute of Non-ferrous Metals and Materials Science

Email: antluba@mail.ru
Rússia, Krasnoyarsk, 660041

V. Denisov

Institute of Non-ferrous Metals and Materials Science

Email: antluba@mail.ru
Rússia, Krasnoyarsk, 660041

L. Denisova

Institute of Non-ferrous Metals and Materials Science

Autor responsável pela correspondência
Email: antluba@mail.ru
Rússia, Krasnoyarsk, 660041

Yu. Kargin

Baikov Institute of Metallurgy and Materials Science

Email: antluba@mail.ru
Rússia, Moscow, 119991

N. Belousova

Institute of Non-ferrous Metals and Materials Science

Email: antluba@mail.ru
Rússia, Krasnoyarsk, 660041

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