Enviar artigo por via de e-mail Identification of B−H···H−C Specific Interactions Observed in Complexes [M(solv)6][B10H10] (M = Co, Ni) by Spectral Analytical Methods
- Autores: Goeva L.V.1, Avdeeva V.V.1, Malinina E.A.1, Kuznetsov N.T.1
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Afiliações:
- Kurnakov Institute of General and Inorganic Chemistry
- Edição: Volume 63, Nº 8 (2018)
- Páginas: 1050-1055
- Seção: Coordination Compounds
- URL: https://journals.rcsi.science/0036-0236/article/view/168902
- DOI: https://doi.org/10.1134/S0036023618080089
- ID: 168902
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Resumo
The B−H···H−C specific interactions observed in complexes [M(solv)6][B10H10], where M= Co(II), Ni(II); solv = DMF or DMSO, are analyzed based on the correlation between the X-ray diffraction data and the results of IR and UV spectroscopic studies. Comparing the experimental data obtained earlier with those reported here allows us to elucidate one of the reasons that do not permit unambiguously determine the presence of long-range contacts when interpreting spectral data.
Sobre autores
L. Goeva
Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Rússia, Moscow, 119991
V. Avdeeva
Kurnakov Institute of General and Inorganic Chemistry
Autor responsável pela correspondência
Email: avdeeva.varvara@mail.ru
Rússia, Moscow, 119991
E. Malinina
Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Rússia, Moscow, 119991
N. Kuznetsov
Kurnakov Institute of General and Inorganic Chemistry
Email: avdeeva.varvara@mail.ru
Rússia, Moscow, 119991
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