Hydrothermal Microwave Synthesis of MnO2 in the Presence of Melamine: The Role of Temperature and pH


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Nanocrystalline manganese dioxide have been prepared by hydrothermal microwave treatment of mixed solutions of potassium permanganate and 2,4,6-triamino-1,3,5-triazine (melamine) in pH range 0.5–3. Phase and chemical composition and morphology of the samples was studied by XRD, Raman spectroscopy, and SEM. Conditions (solution pH and temperature) for the formation of single phase MnO2 powders (α-MnO2, γ-MnO2, δ-MnO2, and δ*-MnO2) under hydrothermal microwave treatment were determined.

作者简介

O. Ivanova

Kurnakov Institute of General and Inorganic Chemistry

Email: a.baranchikov@yandex.ru
俄罗斯联邦, Moscow, 119991

M. Teplonogova

Moscow State University

Email: a.baranchikov@yandex.ru
俄罗斯联邦, Moscow, 119991

A. Yapryntsev

Kurnakov Institute of General and Inorganic Chemistry

Email: a.baranchikov@yandex.ru
俄罗斯联邦, Moscow, 119991

A. Baranchikov

Kurnakov Institute of General and Inorganic Chemistry; Moscow State University

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Email: a.baranchikov@yandex.ru
俄罗斯联邦, Moscow, 119991; Moscow, 119991

V. Ivanov

Kurnakov Institute of General and Inorganic Chemistry; Moscow State University; Moscow Technological University

Email: a.baranchikov@yandex.ru
俄罗斯联邦, Moscow, 119991; Moscow, 119991; Moscow, 119571

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