Structural features of monomeric octahedral d2-rhenium(V) monooxo complexes with the oxygen atoms of bidentate chelate (О,S and О,С) acido ligands
- 作者: Sergienko V.S.1,2
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隶属关系:
- Kurnakov Institute of General and Inorganic Chemistry
- All-Russia Institute of Scientific and Technical Information
- 期: 卷 62, 编号 6 (2017)
- 页面: 751-759
- 栏目: Coordination Compounds
- URL: https://journals.rcsi.science/0036-0236/article/view/167737
- DOI: https://doi.org/10.1134/S0036023617060195
- ID: 167737
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详细
Some structural features of 12 mononuclear octahedral d2-Re(V) monooxo complexes (I–ХII) with the oxygen atoms of bidentate chelate (О,S) acido ligands (Lig) and a similar complex with the oxygen atom of a bidentate chelate (О,С) monoanionic ligand (XIII) have been considered. The O(Lig) atoms are in trans positions to О(oxo) ligands in eleven complexes I–Х and XIII and in cis positions to oxo ligands in two complexes XI and XII. In all the cases, Re–Otrans bonds are longer than Re–Ocis (or Re–Ostand).
作者简介
V. Sergienko
Kurnakov Institute of General and Inorganic Chemistry; All-Russia Institute of Scientific and Technical Information
编辑信件的主要联系方式.
Email: sergienko@igic.ras.ru
俄罗斯联邦, Leninskii pr. 31, Moscow, 119991; ul. Usievicha 20, Moscow, 125190
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