Binuclear copper(II) complexes based on acyldihydrazones of imino-, oxo-, and thiodiacetic acids and 2-hydroxyacetophenone


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Abstract

The results of studying the binuclear copper(II) complexes with acyldihydrazones of amino-, oxo-, and thiodiacetic acids and 2-hydroxyacetophenone were described. The temperature variations of the EPR spectra of solutions with a seven-line hyperfine structure indicating an exchange character of interaction between unpaired electrons and the two equivalent nuclei of copper atoms were studied.

About the authors

O. V. Konnik

V.I. Vernadsky Crimean Federal University

Email: vshul@crimea.edu
Russian Federation, pr. Akademika Vernagskogo 4, Simferopol, Crimea, 295007

V. F. Shul’gin

V.I. Vernadsky Crimean Federal University

Author for correspondence.
Email: vshul@crimea.edu
Russian Federation, pr. Akademika Vernagskogo 4, Simferopol, Crimea, 295007

A. N. Gusev

V.I. Vernadsky Crimean Federal University

Email: vshul@crimea.edu
Russian Federation, pr. Akademika Vernagskogo 4, Simferopol, Crimea, 295007

E. A. Zamnius

V.I. Vernadsky Crimean Federal University

Email: vshul@crimea.edu
Russian Federation, pr. Akademika Vernagskogo 4, Simferopol, Crimea, 295007

V. V. Minin

Kurnakov Institute of General and Inorganic Chemistry

Email: vshul@crimea.edu
Russian Federation, Leninskii pr. 31, Moscow, 119991

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