Structure of Al2Au Intermetallic Compound Obtained by Mechanochemical Synthesis
- 作者: Volkova E.1, Volkov A.1, Antonov B.2
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隶属关系:
- Mikheev Institute of Metal Physics, Ural Branch, Russian Academy of Sciences
- Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences
- 期: 卷 119, 编号 7 (2018)
- 页面: 650-659
- 栏目: Structure, Phase Transformations, and Diffusion
- URL: https://journals.rcsi.science/0031-918X/article/view/167675
- DOI: https://doi.org/10.1134/S0031918X18070128
- ID: 167675
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详细
The structure of Al2Au intermetallic compound mechanically synthesized from a nanoscale gold powder and aluminum particles of about 0.5 mm in size has been studied by X-ray diffraction and transmission and scanning electron microscopy. It has been established that the intermetallic compound is formed as a powder with a particle size of 0.3–3 μm. In addition to intermetallic compound, some aluminum has been found in the powder, along with traces of gold and aluminum oxide Al2O3, and the appearance of an amorphous phase has been registered. The microstructure of compacts formed from the obtained powder has been studied, and heat treatments have been carried out. It has been found that compacting and subsequent annealing contribute to the agglomeration of intermetallic particles. Increasing the treatment temperature to 600°C results in the refinement of the structural elements as a result of their cracking in the surface layer. Compacts that are dark purple in their original state acquire a color ranging from pink to dark red as a result of annealing. After heat treatment, the presence of Al2O3, as well as of intermetallic phases enriched in gold (AlAu and AlAu4), has been detected in compacts in addition to the intermetallic compound Al2Au.
作者简介
E. Volkova
Mikheev Institute of Metal Physics, Ural Branch, Russian Academy of Sciences
编辑信件的主要联系方式.
Email: volkova@imp.uran.ru
俄罗斯联邦, Ekaterinburg, 620108
A. Volkov
Mikheev Institute of Metal Physics, Ural Branch, Russian Academy of Sciences
Email: volkova@imp.uran.ru
俄罗斯联邦, Ekaterinburg, 620108
B. Antonov
Institute of High-Temperature Electrochemistry, Ural Branch, Russian Academy of Sciences
Email: volkova@imp.uran.ru
俄罗斯联邦, Ekaterinburg, 620137