Effect of friction-induced deformation and oxidation on the structure and microhardness of surface aluminum and silumin layers

详细

Metallography, electron microscopy, and X-ray diffraction have been used to investigate structural transformations that take place in a 10-μm-thick surface layer in aluminum and Al–17% Si alloy under conditions of sliding friction and subsequent oxidation at 100 and 200°C for 1 h. Friction-induced deformation has been carried out at room temperature in air and at–196°C in liquid nitrogen by reciprocating sliding of a cylindrical indenter made of cubic boron nitride at a rate of 0.014 m/s and a load of 98 N. It is shown that deformation under these conditions forms nanocrystalline structures in the surface layer in aluminum and Al–17% Si alloy and increases their microhardness by a factor of 1.8–3.5. A high contact deformation and a high affinity of oxygen to aluminum and silicon cause the formation of anomalously supersaturated solid solutions of oxygen in aluminum and silicon in the surface layer of the alloy during friction. Oxidation at 100°C (1 h) of the deformed Al–17% Si alloy increases its microhardness due to the decomposition of anomalously supersaturated solid solutions of oxygen in aluminum and silicon and the formation of their oxides.