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Vol 120, No 6 (2019)

Theory of Metals

Modern Physics of the Condensed State: Strong Correlations and Quantum Topology

Irkhin V.Y., Skryabin Y.N.

Abstract

The theme of this survey is the application of new ideas of uncommon quantum states to the physics of the condensed state, in particular, of solids, in the context of the contemporary field theory. A comparison is performed with the classical works on the many-electron theory, including the formalism of many-electron operators. Principally, the many-particle nature of the ground state, individual and collective excitations, and quantum fluctuations in the systems in question are discussed, as well as quantum phase transitions (mainly, the topological aspects considering the effects of frustration). The variational approaches and the concepts of auxiliary particles, the corresponding mean-field approximations, the theory of gauge fields, the problem of confinement–deconfinement, the breakdown of the Fermi-liquid behavior, and exotic non-Fermi liquid states are considered. A survey of the contemporary theory of the entangled topological states, formation of spin liquid, strings, and string networks is given.

Physics of Metals and Metallography. 2019;120(6):513-548
pages 513-548 views

Electrical and Magnetic Properties

Effect of Crystallizing Annealing on Dynamic Magnetoelastic Properties of the Fe81Si7B12 Amorphous Alloy

Fedorova N.V., Len’kov S.V., Konygin G.N., Nemtsova O.M.

Abstract

The double electromagnetoacoustic transformation method is used to study the dynamic magnetoelastic properties of the Fe81Si7B12 amorphous alloy depending on the temperature of crystallization annealing. Changes found in the velocity of sound, its damping, and differential magnetostriction are related to the relaxation of quenching stresses and the surface crystallization.

Physics of Metals and Metallography. 2019;120(6):549-555
pages 549-555 views

Matrices of Ferromagnetic Microwires for the Control of Cellular Dynamics and Localized Delivery of Medicines

Beklemisheva A.V., Yudanov N.A., Gurevich A.A., Panina L.V., Zablotskiy V.A., Deyneka A.

Abstract

Amorphous ferromagnetic microwires are quite promising for use in various biomedical fields. A microwire in a biocompatible shell can be introduced into soft tissues or into blood vessels to maintain the biofunctioning of magnetic nanoparticles or stem cells with magnetic markers circulating in the blood. The magnetic fields created by the lattices of microwires are characterized by strong spatial gradients and can change over time in a specified manner. Such fields are necessary for the development of various magnetophoretic analytical chips for controlling the kinetics of cells and also for controlled drug delivery. A system of diametrically magnetized microwires is suggested in this paper, which possesses an energy minimum necessary for the stable capture of diamagnetic cells. The suggested dipole system is also promising for the accelerated diffusion transfer of magnetic nanoparticles, which are located in a liquid carrier, due to a gradient magnetic field.

Physics of Metals and Metallography. 2019;120(6):556-562
pages 556-562 views

Temperature of the Formation of a Protective Polymer Coating and the Magnetic Properties of Cobalt-Based Amorphous Alloys

Skulkina N.A., Ivanov O.A., Mazeeva A.K., Kuznetsov P.A., Chekis V.I., Denisov N.D.

Abstract

The influence of the polymer coating used in the manufacture of magnetic shields and of the conditions of its formation on the distribution of the magnetization and on the magnetic properties of shields has been studied. Samples of a ribbon of the Co-based soft-magnetic amorphous alloy AMAG-172 (Co–Ni–Fe–Cr–Mn–Si–B) with a saturation magnetostriction close to zero were used in the study. The coating was deposited in the temperature range of 90–130°C on the ribbon subjected to heat treatments in air that form a state with a negative saturation magnetostriction. The change of magnetic characteristics was investigated over a two year period. It has been shown that there is a temperature range in which a change in the sign of the saturation magnetostriction occurs upon the formation of the coating. This change is due to a change in the structural-phase state of the ribbon because of the diffusion processes that occur upon heating. The formation of the coating leads to a reduction in the maximum magnetic permeability; nevertheless, over a two year period, no decrease in μmax is observed in the ribbon with a coating formed in the 110–130°C temperature range.

Physics of Metals and Metallography. 2019;120(6):563-569
pages 563-569 views

Structure, Phase Transformations, and Diffusion

The Influence of Tensile Stress on the Recrystallization and Texture Stability of Ni–5 at % W Long Tapes

Yu D., Ma L., Suo H.L., Liu J., Ji Y.T., Cui J., Tian H., Gao M.M., Liu M., Wang Y.

Abstract

The microstructure and crystal orientation of Ni–5 at % W (Ni5W) long tapes during recovery and recrystallization processes under various tensile stresses are studied systematically by using a tensile stress annealing equipment designed in our University. Comparing these two processes with and without tensile stresses, it is found that tensile stresses can promote recrystallization, for example: the cube orientation fractions under a tensile stress of 20 MPa is twice as high as without tensile stress at 650°C. In the complete recrystallization process, tensile stresses below 10 MPa have little effect on the microstructure and crystal orientation. When the tensile stress is increased to 25 MPa, the grain boundary grooves are obviously deepened into cracks, while the fractions of both low angle grain boundaries and cube texture decreased. This is in contrast to an increase of the fractions of Σ3 twin boundaries showing a more abnormal grain growth. The effects of tensile stresses on the annealing process of Ni5W long tapes are investigated experimentally. They are expected to guide the reel-to-reel dynamic recrystallization annealing of Ni5W long tapes and to promote the transition from laboratory to industrialization.

Physics of Metals and Metallography. 2019;120(6):570-577
pages 570-577 views

Prediction of Segregation in Binary Metal Nanoparticles: Thermodynamic and Atomistic Simulations

Samsonov V.M., Talyzin I.V., Kartoshkin A.Y., Samsonov M.V.

Abstract

A complex approach based on thermodynamic and atomistic simulations is used to predict segregation in binary metal nanoparticles of Cu–Ni and Ag–Au. The results of thermodynamic simulation within the model of limited source of segregating component agree with those of the atomistic simulation, and both predict the surface segregation of Cu atoms in the Cu–Ni nanoalloys and the segregation of Ag atoms at the surface of the binary Ag–Au nanoparticles.

Physics of Metals and Metallography. 2019;120(6):578-583
pages 578-583 views

Study of the Grain Size Distribution during Preheating Period Prior to the Hot Deformation in AISI 316L Austenitic Stainless Steel

Rasti J.

Abstract

Grain size and its distribution is the dominant microstructure feature of austenitic stainless steels. These characteristics considerably affect the mechanical properties of the steels. The distribution of grain size during preheating prior to the hot deformation has the main effect on the uniform distribution of the strain interior of the grains and, consequently, on the homogeneous development of processes such as static, dynamic, and metadynamic recrystallization in the material. The grain size distribution can be expressed using the Jensen–Gundersen point method along with the commonly-cited distribution functions such as the lognormal, gamma, Weibull, Louat, or Hilert relations. In this study, 3D Monte Carlo Potts method was employed for predicting grain growth kinetics and relevant grain size distribution during annealing process to describe which distribution function is dominant. To validate simulation results, the serial sectioning procedure was performed on AISI 316L cylindrical samples annealed at 1200°C for 5, 10, and 15 min. Results show that grain number densities (GND) affect the grain size distribution, in which at the relatively low GNDs, the lognormal function and at the higher ones, the gamma function are realized. Moreover, a new method for the grain size standard deviation statement via the lognormal distribution is introduced.

Physics of Metals and Metallography. 2019;120(6):584-592
pages 584-592 views

Analysis of the Effect of Hydrostatic Pressure on the Nonvariant Eutectic Transformation in Al–Si, Al–Cu, and Al–Cu–Si Systems

Akopyan T.K., Belov N.A., Padalko A.G., Letyagin N.V., Avksent’yeva N.N.

Abstract

Differential barothermal analysis (DBA) is used to analyze the effect of hydrostatic pressure of 100 MPa on characteristic temperatures of a number of eutectic alloys (wt %), such as Al–10Si, Al–12Si, Al‒22Cu, Al–33Cu, and Al–7Cu–7Si. According to DBA data, the increase in pressure resulted in an increase in the temperatures of phase transformation; in practice, the most important of them is the nonvariant eutectic transformation temperature that determines the solidus of alloys. It was found that, for the binary systems, the temperatures of the nonvariant eutectic transformation L → (Al) + Si and L → (Al) + Al2Cu increase by 6 and 11°С (from 577 to 583°С and from 548 to 559°С, respectively); for the ternary system, the temperature of transformation L → (Al) +Al2Cu + Si increases by 6°С (from 520 to 526°С). Theoretical analysis, performed using thermodynamic models and Thermo-Calc software, shows that the increase in the eutectic transformation temperature with increasing pressure is directly dependent on the relative decrease in the molar volume of system upon associated eutectic transformation. In this case, the excess dissolution of silicon in (Al) under high pressure can lead to an additional decrease in the molar volume of the system, whereas the increase in the copper solubility is thermodynamically unfavorable.

Physics of Metals and Metallography. 2019;120(6):593-599
pages 593-599 views

Strength and Plasticity

Influence of Pressure on the Processes of Formation and Evolution of the Nanostructure in Plastically Deformed Metals and Alloys

Vasil’ev L.S., Lomaev S.L.

Abstract

The role of volume changes on the structural rearrangements of dislocation pileups accompanied by the formation of the intercrystallite boundaries, pores, and microcracks upon the plastic deformation of materials is analyzed. The results of this analysis are applied to the study of the microscopic mechanisms of the effect of pressure on processes of the formation and fracture of the nanostructure of metals and alloys.

Physics of Metals and Metallography. 2019;120(6):600-606
pages 600-606 views

Influence of Severe Dynamic Action on Phase and Structural Transformations in a Metal of Welded Joints

Tabatchikova T.I., Tereshchenko N.A., Morozova A.N., Gudnev N.Z.

Abstract

Optical and scanning electron microscopy, as well as X-ray diffraction analysis, have been used to study the structural changes in the welded joints of steel structures subjected to a local severe dynamic action. It has been shown that after welding, a structure consisting of martensite, δ ferrite, and metastable austenite is formed in the weld metal. The subsequent severe dynamic action leads to a strengthening of the weld metal, which is caused by the transformation of metastable austenite into strain-induced martensite.

Physics of Metals and Metallography. 2019;120(6):607-613
pages 607-613 views

Evolution of Microstructure and Mechanical Properties of a New Al–Cu–Er Wrought Alloy

Pozdnyakov A.V., Barkov R.Y., Sarsenbaev Z., Amer S.M., Prosviryakov A.S.

Abstract

The evolution of the microstructure and mechanical properties of deformed sheets made of a new Al–4Cu–2.7Er alloy has been studied in the course of homogenization and annealing. The structure of the cast alloy consists of a dispersed eutectic ((Al) + Al8Cu4Er), Al3Er-phase inclusions located along the dendritic-cell boundaries, and a nonequilibrium AlCu phase. During annealing at 605°C before quenching, the intermetallic phases have high thermal stability: the particle size of Al8Cu4Er and Al3Er phases does not exceed 1–4 µm. The annealing of deformed sheets at temperatures below 300°C leads to a slight decrease in the hardness; grains elongated along the rolling direction are observed in the structure. With an increase in the annealing temperature from 350 to 550°C, the recrystallized grain size increases from 8 ± 1 to 14.5 ± 1.5 μm. The uniaxial tensile tests showed that the annealed alloy possesses sufficiently high strength characteristics: yield stress of 260–280 MPa, ultimate tensile strength of 291–312 MPa, and relative elongation of 5.5–6.1%.

Physics of Metals and Metallography. 2019;120(6):614-619
pages 614-619 views

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