Отправить статью по E-mail The Local Structure and Hydration Processes of Halogen-Substituted Perovskites Based on Ba4In2Zr2O11
- Авторы: Tarasova N.A.1, Galisheva A.O.1, Animitsa I.E.1
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Учреждения:
- Institute of Natural Sciences and Mathematics, Ural Federal University Named after the First President of Russia B.N. Yeltsin
- Выпуск: Том 126, № 4 (2019)
- Страницы: 336-340
- Раздел: Spectroscopy of Condensed States
- URL: https://journals.rcsi.science/0030-400X/article/view/165960
- DOI: https://doi.org/10.1134/S0030400X19040222
- ID: 165960
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Аннотация
Halogen-substituted perovskites Ba4In2Zr2O10.95F0.1 and Ba4In2Zr2O10.95Cl0.1 are synthesized, and their single-phase composition is verified by X-ray diffraction analysis. Their ability of the studied phases to hydrate and form energetically unequal OH– groups is proved. It is found that introduction of halide ions leads to a decrease in the hydration degree with respect to the matrix composition, which is explained by a decrease in the crystal unit cell free volume Processes.
Об авторах
N. Tarasova
Institute of Natural Sciences and Mathematics,Ural Federal University Named after the First President of Russia B.N. Yeltsin
Автор, ответственный за переписку.
Email: Natalia.Tarasova@urfu.ru
Россия, Yekaterinburg, 620026
A. Galisheva
Institute of Natural Sciences and Mathematics,Ural Federal University Named after the First President of Russia B.N. Yeltsin
Email: Natalia.Tarasova@urfu.ru
Россия, Yekaterinburg, 620026
I. Animitsa
Institute of Natural Sciences and Mathematics,Ural Federal University Named after the First President of Russia B.N. Yeltsin
Email: Natalia.Tarasova@urfu.ru
Россия, Yekaterinburg, 620026
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