Polymer-modified supported palladium catalysts for the hydrogenation of acetylene compounds


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Palladium catalysts supported on zinc oxide modified with polyethylene glycol or pectin were synthesized and investigated in the hydrogenation of acetylene compounds. It was established that the polymercontaining catalysts reduce acetylene hyrbons to olefins with high activity, selectivity, and stability. The composition and structure of the obtained composites were studied by elemental analysis, transmission electron microscopy, and XPS spectroscopy. It was found that the nanosized particles of palladium uniformly immobilized on the surface of zinc oxide were formed in the course of the synthesis of a supported polymer/oxide complex.

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A. Zharmagambetova

Sokol’skii Institute of Organic Catalysis and Electrochemistry

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Email: zhalima@mail.ru
哈萨克斯坦, Almaty, 050010

K. Seitkalieva

Sokol’skii Institute of Organic Catalysis and Electrochemistry

Email: dzhardim@icp.ac.ru
哈萨克斯坦, Almaty, 050010

E. Talgatov

Sokol’skii Institute of Organic Catalysis and Electrochemistry

Email: dzhardim@icp.ac.ru
哈萨克斯坦, Almaty, 050010

A. Auezkhanova

Sokol’skii Institute of Organic Catalysis and Electrochemistry

Email: dzhardim@icp.ac.ru
哈萨克斯坦, Almaty, 050010

G. Dzhardimalieva

Institute of Problems of Chemical Physics

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Email: dzhardim@icp.ac.ru
俄罗斯联邦, Chernogolovka, Moscow oblast, 142432

A. Pomogailo

Sokol’skii Institute of Organic Catalysis and Electrochemistry

Email: dzhardim@icp.ac.ru
哈萨克斯坦, Almaty, 050010

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