Kinetics of the Liquid-Phase Hydrochlorination of Ethanol
- Авторы: Makhin M.N.1, Dmitriev G.S.1, Zanaveskin L.N.1
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Учреждения:
- Topchiev Institute of Petrochemical Synthesis
- Выпуск: Том 59, № 5 (2018)
- Страницы: 553-556
- Раздел: Article
- URL: https://journals.rcsi.science/0023-1584/article/view/163985
- DOI: https://doi.org/10.1134/S0023158418050099
- ID: 163985
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Аннотация
The results of a study on the kinetics of the liquid-phase hydrochlorination of ethanol with hydrogen chloride are presented. The form of the rate equation, the preexponential factor, the activation energy, and the empirical coefficients that characterize the effect of chloride anion hydration on the reaction rate of ethanol hydrochlorination were determined. The rates of hydrochlorination of monohydric alcohols and polyols were compared based on the examples of methanol, ethanol, 1,2-propylene glycol, and glycerol.
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Об авторах
M. Makhin
Topchiev Institute of Petrochemical Synthesis
Автор, ответственный за переписку.
Email: Makhin.Maxim@gmail.com
Россия, Moscow, 119991
G. Dmitriev
Topchiev Institute of Petrochemical Synthesis
Email: Makhin.Maxim@gmail.com
Россия, Moscow, 119991
L. Zanaveskin
Topchiev Institute of Petrochemical Synthesis
Email: Makhin.Maxim@gmail.com
Россия, Moscow, 119991
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