Kinetics of the Liquid-Phase Hydrochlorination of Ethanol
- 作者: Makhin M.N.1, Dmitriev G.S.1, Zanaveskin L.N.1
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隶属关系:
- Topchiev Institute of Petrochemical Synthesis
- 期: 卷 59, 编号 5 (2018)
- 页面: 553-556
- 栏目: Article
- URL: https://journals.rcsi.science/0023-1584/article/view/163985
- DOI: https://doi.org/10.1134/S0023158418050099
- ID: 163985
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详细
The results of a study on the kinetics of the liquid-phase hydrochlorination of ethanol with hydrogen chloride are presented. The form of the rate equation, the preexponential factor, the activation energy, and the empirical coefficients that characterize the effect of chloride anion hydration on the reaction rate of ethanol hydrochlorination were determined. The rates of hydrochlorination of monohydric alcohols and polyols were compared based on the examples of methanol, ethanol, 1,2-propylene glycol, and glycerol.
作者简介
M. Makhin
Topchiev Institute of Petrochemical Synthesis
编辑信件的主要联系方式.
Email: Makhin.Maxim@gmail.com
俄罗斯联邦, Moscow, 119991
G. Dmitriev
Topchiev Institute of Petrochemical Synthesis
Email: Makhin.Maxim@gmail.com
俄罗斯联邦, Moscow, 119991
L. Zanaveskin
Topchiev Institute of Petrochemical Synthesis
Email: Makhin.Maxim@gmail.com
俄罗斯联邦, Moscow, 119991
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