Nontransition metal–crown ether complexes as hydroperoxide decomposition catalysts


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Аннотация

The decomposition of tert-butyl hydroperoxide in a chlorobenzene medium in the presence of complexes of dibenzo-18-crown-6 with calcium, strontium, and barium chlorides has been studied. It has been found and kinetically proven that the decomposition of tert-butyl hydroperoxide is preceded by the formation of an intermediate hydroperoxide–catalyst complex. Kinetic and thermodynamic parameters of the complex formation have been determined.

Авторлар туралы

N. Nurullina

Kazan National Research Technical University

Хат алмасуға жауапты Автор.
Email: nyryllina@mail.ru
Ресей, Kazan, Tatarstan, 420015

N. Batyrshin

Kazan National Research Technical University

Email: nyryllina@mail.ru
Ресей, Kazan, Tatarstan, 420015

Kh. Kharlampidi

Kazan National Research Technical University

Email: nyryllina@mail.ru
Ресей, Kazan, Tatarstan, 420015

V. Anisimova

Kazan National Research Technical University

Email: nyryllina@mail.ru
Ресей, Kazan, Tatarstan, 420015

I. Suvorova

Kazan National Research Technical University

Email: nyryllina@mail.ru
Ресей, Kazan, Tatarstan, 420015

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