Influence of Preparation Method of Ag–CeO2 Catalysts on Their Structure and Activity in Soot Combustion


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The exhaust gases from motor vehicles contain unburned soot particles that pollute the environment and have a detrimental effect on the human health. The solution to this problem requires the development of new highly efficient Pt- and Pd-less catalysts for the oxidation of soot in exhaust gases. In the present work, the catalysts based on the Ag–CeO2 composition were synthesized by two techniques (co-precipitation and incipient wetness impregnation) and characterized by a complex of physicochemical methods (low-temperature nitrogen adsorption, powder X-ray diffraction (XRD), high-resolution transmission electron microscopy (TEM HR) and temperature-programmed oxidation (TPO)). The catalytic properties of the catalysts were studied in the reaction of soot oxidation. It was shown that the Ag–CeO2 catalyst prepared by the coprecipitation method was the most active in soot oxidation. The increased activity of the catalyst was associated with the formation of a complex structure, representing an agglomerate of strongly interacting silver and ceria particles, which significant affect the low-temperature activation of oxygen on the catalyst surface as shown by the TPO method.

作者简介

M. Sadlivskaya

Tomsk State University

Email: GrigoriyMamontov@mail.ru
俄罗斯联邦, Tomsk, 634050

N. Mikheeva

Tomsk State University

Email: GrigoriyMamontov@mail.ru
俄罗斯联邦, Tomsk, 634050

V. Zaikovskii

Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences; Novosibirsk State University

Email: GrigoriyMamontov@mail.ru
俄罗斯联邦, Novosibirsk, 630090; Novosibirsk, 630090

G. Mamontov

Tomsk State University

编辑信件的主要联系方式.
Email: GrigoriyMamontov@mail.ru
俄罗斯联邦, Tomsk, 634050

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