New laser plasma process to obtain solid coatings and their structural characteristics

V. N. Demin; T. P. Smirnova; V. O. Borisov; G. N. Grachev; A. L. Smirnov; M. N. Khomyakov

doi:10.1134/S0022476617080042

New laser plasma process to obtain solid coatings and their structural characteristics

Авторы: Demin V.N.¹, Smirnova T.P.¹, Borisov V.O.¹, Grachev G.N.², Smirnov A.L.², Khomyakov M.N.²
Учреждения:
1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch
2. Institute of Laser Physics, Siberian Branch
Выпуск: Том 58, № 8 (2017)
Страницы: 1503-1509
Раздел: Article
URL: https://journals.rcsi.science/0022-4766/article/view/161688
DOI: https://doi.org/10.1134/S0022476617080042
ID: 161688

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Аннотация

Carbon nitride coatings are synthesized in the new laser plasma of powerful optical pulsating discharge using acetonitrile as a precursor. A high-pressure and -temperature C₃N₄ cubic phase with a spinel structure type is obtained. The microhardness of coatings of this structure type is ~45 gPa. The chemical composition and structure of the coatings are characterized by a complex of spectroscopic (IR, Raman, EDS) techniques as well as microscopic (AFM and XRD) techniques.