Structure of a gadolinium coordination compound with acyldihydrazone of adipic acid and 3-methyl-1-phenyl-4-formylpyrazol-5-one

Аннотация

The structure of a gadolinium coordination compound with acyldihydrazone of adipic acid and 3-methyl-1-phenyl-4-formylpyrazol-5-one is studied by the XRD. It is determined that the compound is built as a spacer-armed dinuclear complex in which coordination polyhedra are linked by three aliphatic bridges packed in the asymmetric triple helix. The coordination polyhedron of the gadolinium cation has a slightly distorted three-capped trigonal prism geometry.