Structure of Two Complexes of N-Thiophosphorylated Thioamides with a Silver(I) Cation and Triphenylphosphine

Resumo

In order to study the complexation properties of N-thiophosphorylated thioureas, thioamides, and thiosemicarbazides with the general formula RC(S)NHP(S)(OPrⁱ)₂ (R = AlkNH, Alk₂N, ArNH, PyNH, Ph, PhNHNH, NH₂(Et)N) towards copper(I) and silver(I) cations, the molecular and crystal structures of silver(I) (triphenylphosphine-P)[N-(diisopropoxythiophosphoryl)thiobenzamide-S,S′] and silver(I) bis-(triphenylphosphine-P)[N-(diisopropoxythiophosphoryl)thiobenzamide-S,S′] are determined.