In situ X-ray spectroscopic investigation of thermal decomposition of double complex salt [Pt(NH3)4][OsCl6]


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In the paper results of the investigation of the thermal decomposition process of double complex salt [Pt(NH3)4][OsCl6] by x-ray absorption (XAFS) and photoelectron (XPS) spectroscopies have been presented. The data obtained allows a mechanism of the thermal decomposition to be refined. An influence of size effect and nanoalloy formation on chemical shift of Pt and Os is discussed.

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T. Asanova

Nikolaev Institute of Inorganic Chemistry Siberian Branch

编辑信件的主要联系方式.
Email: nti@niic.nsc.ru
俄罗斯联邦, Novosibirsk

I. Asanov

Nikolaev Institute of Inorganic Chemistry Siberian Branch; Novosibirsk National Research University

Email: nti@niic.nsc.ru
俄罗斯联邦, Novosibirsk; Novosibirsk

M.-G. Kim

Beamline Research Division

Email: nti@niic.nsc.ru
韩国, Pohang

S. Korenev

Nikolaev Institute of Inorganic Chemistry Siberian Branch; Novosibirsk National Research University

Email: nti@niic.nsc.ru
俄罗斯联邦, Novosibirsk; Novosibirsk

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