Radiation synthesis of tetrafluoroethylene telomers with functional hydroxyl and amino end groups in Freon 113

P. P. Kushch; G. A. Kichigina; D. P. Kiryukhin; D. Ya. Barinov

doi:10.1134/S0018143918010071

Radiation synthesis of tetrafluoroethylene telomers with functional hydroxyl and amino end groups in Freon 113

Autores: Kushch P.P.¹, Kichigina G.A.¹, Kiryukhin D.P.¹, Barinov D.Y.²
Afiliações:
1. Institute of Problems of Chemical Physics
2. All-Russia Research Institute of Aviation Materials
Edição: Volume 52, Nº 1 (2018)
Páginas: 52-57
Seção: Radiation Chemistry
URL: https://journals.rcsi.science/0018-1439/article/view/157320
DOI: https://doi.org/10.1134/S0018143918010071
ID: 157320

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Resumo

The kinetics of radiation telomerization of tetrafluoroethylene in Freon 113 with ethanol and ammonia additives have been studied by kinetic calorimetry. Tetrafluoroethylene telomers with terminal hydroxyl and amino groups have been obtained. The molecular structure, properties, and composition of the telomers have been investigated by IR spectroscopy, thermogravimetry, and elemental analysis.