Geochemistry of fractionation of coherent elements (Zr and Hf) during the profound differentiation of peralkaline magmatic systems: A case study of the Lovozero Complex

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The paper presents pioneering data on Hf distribution in peralkaline rocks, ores, and rock-forming and accessory minerals of the Lovozero Complex. Variations in the Zr/Hf ratio are determined in all rocks of the Lovozero alkaline massif. This ratio is proved to increase in the course of evolution of alkaline magma because of fractionation of alkaline pyroxene. The Hf distribution coefficient is evaluated for alkali-rich pyroxene, whose crystallization controls Zr and Hf fractionation during the differentiation of alkaline magma. These data and the equation of equilibrium and fractional crystallization are utilized in a model suggested for Zr and Hf fractionation in the course of evolution of the Lovozero intrusion.