STUDY OF MAGNETIC PHASE TRANSITIONS IN La0.75Sm0.25Mn2Si2 COMPOUND USING 57Fe PROBE MO¨ SSBAUER SPECTROSCOPY

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Аннотация

The compound La0.75Sm0.25Mn2Si2 has been studied by the 57Fe probe M¨ossbauer spectroscopy with the aim to determine magnetic and electronic states of Mn atoms and their changes upon magnetic phase transitions. M¨ossbauer spectra of the model compound La0.75Sm0.25(Mn0.99Fe0.01)2Si2 doped with 57Fe isotope were measured at different temperatures, their fitting and analysis of the obtained hyperfine parameters of different subspectra have been performed. It is shown that the degree of oxygenation of Mn and magnitude of its magnetic moment remain unchanged in the course of the first-order antiferromagnetferromagnet transition. The chemical Mn–Si bonds in the compound are stated to be covalent. The angels of deviation of Mn magnetic moments from the с-axis and their changes with temperature are determined.

Авторлар туралы

Sergey Naumov

Mikheev Institute of Metal Physics, Ural Branch of the Russian Academy of Sciences

Хат алмасуға жауапты Автор.
Email: naumov_sp@imp.uran.ru
ORCID iD: 0000-0003-4354-254X
Ресей, Ekaterinburg, 620108

Alexandr Bartashevich

Mikheev Institute of Metal Physics, Ural Branch of the Russian Academy of Sciences

Email: bartashevich@imp.uran.ru
ORCID iD: 0000-0003-1406-5537
Ресей, Ekaterinburg, 620108

Evgeniy Gerasimov

Mikheev Institute of Metal Physics, Ural Branch of the Russian Academy of Sciences

Email: gerasimov@imp.uran.ru
ORCID iD: 0000-0002-1975-705X
Ресей, Ekaterinburg, 620108

Nikolay Mushnikov

Mikheev Institute of Metal Physics, Ural Branch of the Russian Academy of Sciences

Email: mushnikov@imp.uran.ru
ORCID iD: 0000-0002-6354-2558
Ресей, Ekaterinburg, 620108

Pavel Terentev

Mikheev Institute of Metal Physics, Ural Branch of the Russian Academy of Sciences

Email: terentev@imp.uran.ru
ORCID iD: 0000-0002-2348-6459
Ресей, Ekaterinburg, 620108

Vasiliy Gaviko

Mikheev Institute of Metal Physics, Ural Branch of the Russian Academy of Sciences

Email: gaviko@imp.uran.ru
ORCID iD: 0000-0002-9841-9293
Ресей, Ekaterinburg, 620108

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