Spectroelectrochemical determination of the redox equivalent of magnesium porphine in the course of its electrooxidation


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Abstract

The spectroelectrochemical method has been applied for studying the electropolymerization of magnesium porphine with the aim to determine the number of electrons consumed per monomer molecule, which allows one to find out the number of bonds between the units in the resulting polymer. Based on the results, a conclusion has been made about the structure of macrochains of the basic representative of a new family of electroactive materials, magnesium porphine

About the authors

E. M. Antipov

Mendeleev Russian University of Chemical Technology; Moscow State University

Email: dkfrvzh@gmail.com
Russian Federation, Miusskaya pl. 9, Moscow, 125047; Moscow, 119991

S. M. Aldoshin

Institute of Problems of Chemical Physics; Moscow State University

Email: dkfrvzh@gmail.com
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432; Moscow, 119991

O. I. Istakova

Institute of Problems of Chemical Physics; Mendeleev Russian University of Chemical Technology

Email: dkfrvzh@gmail.com
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432; Miusskaya pl. 9, Moscow, 125047

D. V. Konev

Institute of Problems of Chemical Physics; Mendeleev Russian University of Chemical Technology

Author for correspondence.
Email: dkfrvzh@gmail.com
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432; Miusskaya pl. 9, Moscow, 125047

M. A. Vorotyntsev

Institute of Problems of Chemical Physics; Mendeleev Russian University of Chemical Technology; Moscow State University

Email: dkfrvzh@gmail.com
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432; Miusskaya pl. 9, Moscow, 125047; Moscow, 119991

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