Kinetics of a bimolecular chemical reaction in the liquid phase with association of both reactants


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Mathematical modeling of a bimolecular chemical reaction in the liquid phase was carried out taking account of association of both reactants. The formally simple chemical reaction is thus transformed into a multistage process, which results in the formation of temporal dissipative structures. It was found that, apart from the usual dynamic modes, there appear oscillations of the concentrations of intermediates, characterized by two considerably differing periods.

Sobre autores

T. Kulagina

Institute of Problems of Chemical Physics

Autor responsável pela correspondência
Email: tan@icp.ac.ru
Rússia, Chernogolovka, Moscow oblast, 142432

L. Smirnov

Institute of Problems of Chemical Physics

Email: tan@icp.ac.ru
Rússia, Chernogolovka, Moscow oblast, 142432

Z. Andrianova

Institute of Problems of Chemical Physics

Email: tan@icp.ac.ru
Rússia, Chernogolovka, Moscow oblast, 142432

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