Electrocatalytic activity of palladium–polypyrrole nanocomposite in the formaldehyde oxidation reaction


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Resumo

Palladium–polypyrrole nanocomposite materials with high electrocatalytic activity toward formaldehyde in an alkaline solution (methylene glycolate) have been synthesized via a one-step redox route. Key factors that have an effect on the sensor properties of palladium nanoparticles have been determined. It has been demonstrated for the first time that the emergence of not only the forward but also the reverse wave of formaldehyde oxidation on palladium particles is associated with the oxidation of methylene glycolate rather than intermediate species.

Sobre autores

K. Gor’kov

Moscow State University

Autor responsável pela correspondência
Email: gorkovk@yandex.ru
Rússia, Moscow, 119991

E. Zolotukhina

Institute of Problems of Chemical Physics

Email: gorkovk@yandex.ru
Rússia, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432

E. Mustafina

Moscow State University

Email: gorkovk@yandex.ru
Rússia, Moscow, 119991

M. Vorotyntsev

Institute of Problems of Chemical Physics

Email: gorkovk@yandex.ru
Rússia, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432

E. Antipov

Moscow State University

Email: gorkovk@yandex.ru
Rússia, Moscow, 119991

S. Aldoshin

Moscow State University; Institute of Problems of Chemical Physics

Email: gorkovk@yandex.ru
Rússia, Moscow, 119991; pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432

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