Addition Polymerization of 5-Ethylidene-2-Norbornene in the Presence of Pd N-Heterocyclic Carbene Complexes
- 作者: Topchiy M.1, Gribanov P.1, Nechaev M.1,2, Bermeshev M.1,3, Karpov G.1, Bermesheva E.1, Zudina A.1,4, Asachenko A.1, Minaeva L.5
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隶属关系:
- Topchiev Institute of Petrochemical Synthesis
- Moscow State University
- Mendeleev University of Chemical Technology of Russia
- Sechenov First Moscow State Medical University (1st MSMU)
- OOO INSILIKO
- 期: 卷 479, 编号 2 (2018)
- 页面: 49-52
- 栏目: Chemistry
- URL: https://journals.rcsi.science/0012-5008/article/view/154185
- DOI: https://doi.org/10.1134/S0012500818040031
- ID: 154185
如何引用文章
详细
New high-performance catalytic systems based on Pd N-heterocyclic carbene complexes for the selective addition polymerization of 5-ethylidene-2-norbornene (ENB) were proposed. With these catalysts, polymerization can be conducted at unprecedentedly high monomer/catalyst ratio (up to 5 × 105/1) and gives high-molecular-weight soluble polymers with good film-forming properties. Varying the polymerization conditions (reaction temperature, monomer and catalyst concentrations, monomer/Pd ratio) makes it possible to prepare soluble ENB-based addition polymers with specified molecular weights in reasonable yields.
作者简介
M. Topchiy
Topchiev Institute of Petrochemical Synthesis
Email: bmv@ips.ac.ru
俄罗斯联邦, Moscow, 119991
P. Gribanov
Topchiev Institute of Petrochemical Synthesis
Email: bmv@ips.ac.ru
俄罗斯联邦, Moscow, 119991
M. Nechaev
Topchiev Institute of Petrochemical Synthesis; Moscow State University
Email: bmv@ips.ac.ru
俄罗斯联邦, Moscow, 119991; Moscow, 119991
M. Bermeshev
Topchiev Institute of Petrochemical Synthesis; Mendeleev University of Chemical Technology of Russia
编辑信件的主要联系方式.
Email: bmv@ips.ac.ru
俄罗斯联邦, Moscow, 119991; Moscow, 125047
G. Karpov
Topchiev Institute of Petrochemical Synthesis
Email: bmv@ips.ac.ru
俄罗斯联邦, Moscow, 119991
E. Bermesheva
Topchiev Institute of Petrochemical Synthesis
Email: bmv@ips.ac.ru
俄罗斯联邦, Moscow, 119991
A. Zudina
Topchiev Institute of Petrochemical Synthesis; Sechenov First Moscow State Medical University (1st MSMU)
Email: bmv@ips.ac.ru
俄罗斯联邦, Moscow, 119991; Moscow, 119992
A. Asachenko
Topchiev Institute of Petrochemical Synthesis
Email: bmv@ips.ac.ru
俄罗斯联邦, Moscow, 119991
L. Minaeva
OOO INSILIKO
Email: bmv@ips.ac.ru
俄罗斯联邦, Moscow, 143026