Hydride lithiation of spinels LiMn 2 O 4

G. A. Buzanov; G. D. Nipan; K. Yu. Zhizhin; N. T. Kuznetsov

doi:10.1134/S0012500816110082

Hydride lithiation of spinels LiMn₂O₄

作者: Buzanov G.¹, Nipan G.¹, Zhizhin K.¹, Kuznetsov N.¹
隶属关系:
1. Kurnakov Institute of General and Inorganic Chemistry
期: 卷 471, 编号 1 (2016)
页面: 330-333
栏目: Chemistry
URL: https://journals.rcsi.science/0012-5008/article/view/153820
DOI: https://doi.org/10.1134/S0012500816110082
ID: 153820

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Undoped lithiation of stoichiometric spinel using lithium hydride LiH up to the composition Li_2.25Mn₂O₄ was performed. A homogeneous material with a given Li: Mn ratio was obtained by mechanochemical activation with sequential annealing of a LiMn₂O₄–LiH mixture in a high-purity argon atmosphere and then in air or oxygen at 373–553 K.