Polymers with Regular Alternation of 1,7-Bis[(dimethyl)silylmethylene]-m-carborane and Diorganosiloxane Units
- Авторы: Izmaylov B.1, Vasnev V.1, Markova G.1
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Учреждения:
- Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
- Выпуск: Том 488, № 2 (2019)
- Страницы: 249-251
- Раздел: Chemistry
- URL: https://journals.rcsi.science/0012-5008/article/view/154523
- DOI: https://doi.org/10.1134/S001250081910001X
- ID: 154523
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Аннотация
New highly thermally stable carboranylmethyl-containing diorganosiloxane polymers were obtained by polycondensation of equimolar amounts of 1.7-bis[hydroxy(dimethyl)silylmethylene]-m-carborane and bis(dimethylamino)diorganosilanes. It was shown that replacement of 24 to 33 mol % of dimethylsiloxane units in the polymer backbone by methyl(phenyl)siloxane or diphenylsiloxane units containing bulky phenyl groups results in the formation of only amorphous polymers. The polymers are readily soluble in organic solvents and have high thermal stability.
Об авторах
B. Izmaylov
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: mgaly@yandex.ru
Россия, Moscow, 119991
V. Vasnev
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Email: mgaly@yandex.ru
Россия, Moscow, 119991
G. Markova
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences
Автор, ответственный за переписку.
Email: mgaly@yandex.ru
Россия, Moscow, 119991