1,3,5,7-Tetrasubstituted adamantanes as frameworks in the design of assemblies of porphyrin macrocycles
- Авторы: Vainer A.1, Dyumaev K.1, Kovalenko A.1, Berenshtein L.1, Krichevskaya S.1, Fridzon R.1
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Учреждения:
- All-Russian Research Institute of Medicinal and Aromatic Plants
- Выпуск: Том 474, № 2 (2017)
- Страницы: 129-132
- Раздел: Chemistry
- URL: https://journals.rcsi.science/0012-5008/article/view/154002
- DOI: https://doi.org/10.1134/S0012500817060039
- ID: 154002
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Аннотация
A new strategy for the synthesis of adamantane-containing polyphenols of a porphyrin series has been suggested on the basis of Suzuki–Miyaura reaction between 1,3,5,7-tetrakis(4'-iodophenyl)adamantane and a monoboryl derivative of substituted porphyrin. The synthesis of this porphyrin assembly on the adamantane core followed by chemical transformations of this compound has provided a possibility to synthesize the corresponding polyphenol derivative. The latter has been used in the development of positive photoresists for nanolithography with exposure to radiation at a wavelength 13.5 nm capable of producing topological structures with a resolution of 16 nm.
Об авторах
A. Vainer
All-Russian Research Institute of Medicinal and Aromatic Plants
Автор, ответственный за переписку.
Email: nvbarannik@mail.ru
Россия, Moscow, 117216
K. Dyumaev
All-Russian Research Institute of Medicinal and Aromatic Plants
Email: nvbarannik@mail.ru
Россия, Moscow, 117216
A. Kovalenko
All-Russian Research Institute of Medicinal and Aromatic Plants
Email: nvbarannik@mail.ru
Россия, Moscow, 117216
L. Berenshtein
All-Russian Research Institute of Medicinal and Aromatic Plants
Email: nvbarannik@mail.ru
Россия, Moscow, 117216
S. Krichevskaya
All-Russian Research Institute of Medicinal and Aromatic Plants
Email: nvbarannik@mail.ru
Россия, Moscow, 117216
R. Fridzon
All-Russian Research Institute of Medicinal and Aromatic Plants
Email: nvbarannik@mail.ru
Россия, Moscow, 117216