Effect of small amounts of metal/carbon nanocomposites on the properties of polymer materials


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Metal/carbon nanocomposites have been studied by electron paramagnetic resonance (EPR) and X-ray photoelectron spectroscopy (XPS). EPR study has revealed the existence of delocalized electrons on the carbon shells and the presence of reduced paramagnetic states of nickel in the nickel/carbon nanocomposite. XPS has detected the change in the atomic magnetic moment of the metal. For polycarbonate as an example, conditions for modification of the polymer composition with small amounts of metal/carbon nanoparticles (0.01–0.0001%) have been determined. On the basis of the data obtained, a mechanism of the effect of metal/carbon nanoparticles on the structure and properties of polymer materials has been suggested.

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A. Lipanov

Keldysh Institute of Applied Mathematics

Email: vera_kodolova@mail.ru
俄罗斯联邦, Miusskaya pl. 4, Moscow, 125047

V. Kodolov

Kalashnikov Izhevsk State Technical University

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Email: vera_kodolova@mail.ru
俄罗斯联邦, ul. Studencheskaya 7, Izhevsk, 426069

M. Melnikov

Department of Chemistry

Email: vera_kodolova@mail.ru
俄罗斯联邦, Moscow, 119991

V. Trineeva

Institute of Mechanics, Ural Branch

Email: vera_kodolova@mail.ru
俄罗斯联邦, ul. T. Baramzinoi 34, Izhevsk, 426067

V. Pergushov

Department of Chemistry

Email: vera_kodolova@mail.ru
俄罗斯联邦, Moscow, 119991

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