Effect of bulky substituents on the photochromic properties of indoline spiropyrans containing an annelated aromatic or heteroaromatic fragment


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Abstract

Novel indoline spiropyrans containing bulky neopentyl substituents at the nitrogen atom of the indoline fragment were prepared. The structure of the obtained compounds was established by a set of physicochemical methods of analysis. Comparison was made for the spectral absorption and kinetic parameters of the obtained compounds and their analogs containing methyl and benzyl substituents instead of neopentyl ones.

About the authors

R. V. Tyurin

Research Institute of Physical and Organic Chemistry

Author for correspondence.
Email: wingerover@yandex.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344104

B. S. Lukyanov

Research Institute of Physical and Organic Chemistry

Email: wingerover@yandex.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344104

A. V. Chernyshev

Research Institute of Physical and Organic Chemistry

Email: wingerover@yandex.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344104

V. I. Malay

Research Institute of Physical and Organic Chemistry

Email: wingerover@yandex.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344104

A. S. Kozlenko

Research Institute of Physical and Organic Chemistry

Email: wingerover@yandex.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344104

N. S. Tkacheva

Institute of Problems in Chemical Physics

Email: wingerover@yandex.ru
Russian Federation, pr. Akademika Semenova 1, Chernogolovka, Moscow oblast, 142432

O. N. Burov

Southern Federal University

Email: wingerover@yandex.ru
Russian Federation, ul. Zorge 7, Rostov-on-Don, 344104

M. B. Lukyanova

Research Institute of Physical and Organic Chemistry

Email: wingerover@yandex.ru
Russian Federation, pr. Stachki 194/2, Rostov-on-Don, 344104

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