Email this article New routes to the preparation of gem-cyclopentenedicarboxylic acid derivatives
- Authors: Raskil’dina G.Z.1, Borisova Y.G.1, Yanybin V.M.2, Sultanova R.M.3, Spirikhin L.V.3, Zlotskii S.S.1
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Affiliations:
- Ufa State Oil Technical University
- Institute of Oil Chemistry and Catalysis, Ufa Research Center
- Institute of Organic Chemistry, Ural Branch
- Issue: Vol 466, No 1 (2016)
- Pages: 8-10
- Section: Chemistry
- URL: https://journals.rcsi.science/0012-5008/article/view/153558
- DOI: https://doi.org/10.1134/S0012500816010043
- ID: 153558
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Abstract
A new route was developed to design esters of gem-dicarboxylic acids of cyclopentene series by CH alkylation of diethyl malonate with cis-1,4-dichlorobutene. Diethyl cyclopent-3-ene-1,1-dicarboxylate was reacted with dichlorocarbene. The structures of the isolated compounds were described in detail by 1H, 13C NMR spectroscopy and GC–MS.
About the authors
G. Z. Raskil’dina
Ufa State Oil Technical University
Author for correspondence.
Email: graskildina444@mail.ru
Russian Federation, ul. Kosmonavtov 1, Ufa, 450062
Yu. G. Borisova
Ufa State Oil Technical University
Email: graskildina444@mail.ru
Russian Federation, ul. Kosmonavtov 1, Ufa, 450062
V. M. Yanybin
Institute of Oil Chemistry and Catalysis, Ufa Research Center
Email: graskildina444@mail.ru
Russian Federation, pr. Oktyabrya 141, Ufa, 450075
R. M. Sultanova
Institute of Organic Chemistry, Ural Branch
Email: graskildina444@mail.ru
Russian Federation, pr. Oktyabrya 71, Ufa, 450054
L. V. Spirikhin
Institute of Organic Chemistry, Ural Branch
Email: graskildina444@mail.ru
Russian Federation, pr. Oktyabrya 71, Ufa, 450054
S. S. Zlotskii
Ufa State Oil Technical University
Email: graskildina444@mail.ru
Russian Federation, ul. Kosmonavtov 1, Ufa, 450062
