Oxidation of ASD-4 Powder Modified by V2O5


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The sequence of phase formation in the oxidation of ASD-4 aluminum powder modified by vanadium pentoxide during heating in air in the temperature range 873–1073 K has been studied by synchrotron radiation x-ray diffraction. It has been shown that the sharp acceleration of the oxidation of the modified powder is related to the loss of the protective properties of the oxide shell on the particle surface due to the polyvalence of vanadium, which provides structural and phase changes on the surface and in the depth of the oxidized metal.

作者简介

V. Shevchenko

Institute of Solid State Chemistry

编辑信件的主要联系方式.
Email: shevchenko@ihim.uran.ru
俄罗斯联邦, Ekaterinburg, 620990

D. Eselevich

Institute of Solid State Chemistry

Email: shevchenko@ihim.uran.ru
俄罗斯联邦, Ekaterinburg, 620990

N. Popov

Institute of Solid State Chemistry

Email: shevchenko@ihim.uran.ru
俄罗斯联邦, Ekaterinburg, 620990

V. Krasil’nikov

Institute of Solid State Chemistry

Email: shevchenko@ihim.uran.ru
俄罗斯联邦, Ekaterinburg, 620990

Z. Vinokurov

Boreskov Institute of Catalysis

Email: shevchenko@ihim.uran.ru
俄罗斯联邦, Novosibirsk, 630090

A. Ancharov

Novosibirsk State University; Budker Institute of Nuclear Physics

Email: shevchenko@ihim.uran.ru
俄罗斯联邦, Novosibirsk, 630090; Novosibirsk, 630090

B. Tolochko

Budker Institute of Nuclear Physics; Institute of Solid State Chemistry and Mechanochemistry

Email: shevchenko@ihim.uran.ru
俄罗斯联邦, Novosibirsk, 630090; Novosibirsk, 630128

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