Promoting effect of halogen- and phosphorus-containing flame retardants on the autoignition of a methane–oxygen mixture

A. V. Drakon; A. V. Eremin; O. P. Korobeinichev; V. M. Shvartsberg; A. G. Shmakov

doi:10.1134/S0010508216040018

Promoting effect of halogen- and phosphorus-containing flame retardants on the autoignition of a methane–oxygen mixture

作者: Drakon A.V.¹, Eremin A.V.¹, Korobeinichev O.P.², Shvartsberg V.M.², Shmakov A.G.²^,3
隶属关系:
1. Joint Institute for High Temperatures
2. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch
3. Novosibirsk State University
期: 卷 52, 编号 4 (2016)
页面: 375-385
栏目: Article
URL: https://journals.rcsi.science/0010-5082/article/view/152553
DOI: https://doi.org/10.1134/S0010508216040018
ID: 152553

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This paper presents a numerical and experimental study of the effect of flame-retardant additives on the autoignition of methane behind shock waves. It is shown that at a temperature of 1300–1900 K, the compounds CCl₄, CF₃H, and (CH₃O)₃PO not only do not suppress ignition but significantly reduce the induction time of methane–oxygen mixtures. A kinetic mechanism is proposed which relates the promoting effect to the reactivity of the pyrolysis products of the additives.