Oxidative Cleavage of Asphaltenes Under Mild Conditions
- 作者: Borisov D.1, Foss L.1, Shabalin K.1, Musin L1, Musin R.2
-
隶属关系:
- Federal Research Center, Kazan Scientific Center, RussianAcademy of Sciences
- A. E. Arbuzov Institute of Organic and Physical Chemistry, FRC, Kazan Scientific Center, RAS
- 期: 卷 55, 编号 5 (2019)
- 页面: 552-556
- 栏目: Article
- URL: https://journals.rcsi.science/0009-3092/article/view/235984
- DOI: https://doi.org/10.1007/s10553-019-01065-x
- ID: 235984
如何引用文章
详细
Products from oxidation of asphaltenes by peracetic acid, sodium periodate, and potassium iodate were analyzed using IR spectroscopy and mass spectrometry. Oxidative destruction of asphaltenes increased the aromaticity in their molecular structures and the branching of aliphatic substituents on the polycondensed core. Occluded low-molecular-mass alkanes and cycloalkanes were released during the oxidation. The molecular mass of the asphaltenes changed as a function of the oxidant strength. Asphaltenes fragmented by the acetylene mechanism if the soft oxidant KIO3 was used.
作者简介
D. Borisov
Federal Research Center, Kazan Scientific Center, RussianAcademy of Sciences
Email: iacw212@gmail.com
俄罗斯联邦, Kazan
L. Foss
Federal Research Center, Kazan Scientific Center, RussianAcademy of Sciences
编辑信件的主要联系方式.
Email: iacw212@gmail.com
俄罗斯联邦, Kazan
K. Shabalin
Federal Research Center, Kazan Scientific Center, RussianAcademy of Sciences
Email: iacw212@gmail.com
俄罗斯联邦, Kazan
L Musin
Federal Research Center, Kazan Scientific Center, RussianAcademy of Sciences
Email: iacw212@gmail.com
俄罗斯联邦, Kazan
R. Musin
A. E. Arbuzov Institute of Organic and Physical Chemistry, FRC, Kazan Scientific Center, RAS
Email: iacw212@gmail.com
俄罗斯联邦, Kazan