Synthesis of Hydrocarbon Resins by Thermal Polymerization of Unsaturated Compounds of Pyrolysis Fractions
- Autores: Zakharyan E.M.1, Petrukhina N.N.1, Dmitriev A.I.2, Nekhaev A.I.1, Tumanyan B.P.2, Maksimov A.L.1,3
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Afiliações:
- A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
- Gubkin Russian State University of Oil and Gas (National Research University)
- M. V. Lomonosov Moscow State University, Chemical Department
- Edição: Volume 54, Nº 3 (2018)
- Páginas: 299-306
- Seção: Article
- URL: https://journals.rcsi.science/0009-3092/article/view/235496
- DOI: https://doi.org/10.1007/s10553-018-0927-6
- ID: 235496
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Resumo
Hydrocarbon resins were synthesized by thermal polymerization of the olefinic compounds of liquid pyrolysis products (the C9+ fraction, heavy tar). The hydrocarbon resins were characterized by 1H NMR spectroscopy, MALDI spectroscopy, and gel permeation chromatography. The effect of temperature, reaction time, feed composition, and solvent content on the yield, molecular weight, color, and molecular structure of the hydrocarbon resins was investigated. It was shown that addition of the C9+ fraction to heavy tar increases the polymer yield while reducing the content of aromatic fragments in its structure.
Sobre autores
E. Zakharyan
A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: n.petrukhina@ips.ac.ru
Rússia, Moscow
N. Petrukhina
A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Autor responsável pela correspondência
Email: n.petrukhina@ips.ac.ru
Rússia, Moscow
A. Dmitriev
Gubkin Russian State University of Oil and Gas (National Research University)
Email: n.petrukhina@ips.ac.ru
Rússia, Moscow
A. Nekhaev
A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Email: n.petrukhina@ips.ac.ru
Rússia, Moscow
B. Tumanyan
Gubkin Russian State University of Oil and Gas (National Research University)
Email: n.petrukhina@ips.ac.ru
Rússia, Moscow
A. Maksimov
A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences; M. V. Lomonosov Moscow State University, Chemical Department
Email: n.petrukhina@ips.ac.ru
Rússia, Moscow; Moscow
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