Inorganic MaterialsInorganic MaterialsНеорганические материалы0002-337X3034-5588The Russian Academy of Sciences23191810.31857/S0002337X23070047PUBIKWArticlesСтатьиUnknownComposition and Structure of Mn/Sr-Cosubstituted Tricalcium Phosphate Prepared by Solid-State SynthesisСостав и структура Mn,Sr-замещенного трикальцийфосфата, полученного методом твердофазного синтезаFadeevaI. V.ФадееваИ. В.fadeeva_inna@mail.ruForysenkovaA. A.ФорысенковаА. А.fadeeva_inna@mail.ruFominA. S.ФоминА. С.dvdr@list.ruMikhailovaA. B.МихайловаА. Б.fadeeva_inna@mail.ruAndreevaN. A.АндрееваН. А.fadeeva_inna@mail.ruPenkinaT. N.ПенкинаТ. Н.fadeeva_inna@mail.ruAntonovaO. S.АнтоноваО. С.dvdr@list.ruBarinovS. M.БариновС. М.dvdr@list.ruBaikov Institute of Metallurgy and Materials Science, Russian Academy of SciencesИнститут металлургии и материаловедения им. А.А. Байкова Российской академии наукBaikov Institute of Metallurgy and Materials Science, Russian Academy of SciencesИнститут металлургии и материаловедения им. А.А. Байкова Российской академии наук0107202359779680025122023Copyright ©; 2023, И.В. Фадеева, А.А. Форысенкова, А.С. Фомин, А.Б. Михайлова, Н.А. Андреева, Т.Н. Пенкина, О.С. Антонова, С.М. БариновCopyright ©; 2023, И.В. Фадеева, А.А. Форысенкова, А.С. Фомин, А.Б. Михайлова, Н.А. Андреева, Т.Н. Пенкина, О.С. Антонова, С.М. Баринов2023И.В. Фадеева, А.А. Форысенкова, А.С. Фомин, А.Б. Михайлова, Н.А. Андреева, Т.Н. Пенкина, О.С. Антонова, С.М. БариновИ.В. Фадеева, А.А. Форысенкова, А.С. Фомин, А.Б. Михайлова, Н.А. Андреева, Т.Н. Пенкина, О.С. Антонова, С.М. Бариновhttps://journals.rcsi.science/0002-337X/article/view/231918

Unsubstituted tricalcium phosphate (TCP) and Mn/Sr-cosubstituted TCP have been prepared by solid-state synthesis at 1200°C. The synthesized compounds have been characterized by X-ray diffraction, IR spectroscopy, and scanning electron microscopy. The results indicate that solid-state synthesis of TCP and Mn,Sr-TCP yields compounds with the whitlockite structure. We have determined their lattice parameters and demonstrated the incorporation of the manganese and strontium ions into the structure of TCP.

Твердофазным синтезом при 1200°С получены трикальцийфосфат и Mn,Sr-замещенный трикальцийфосфат (ТКФ). Синтезированные соединения охарактеризованы методами РФА, ИК-спектроскопии, СЭМ. Показано, что в результате твердофазного синтеза ТКФ и Mn,Sr-ТКФ формируются соединения со структурой витлокита. Определены параметры кристаллической решетки и установлен факт внедрения ионов марганца и стронция в структуру ТКФ.

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