Inorganic MaterialsInorganic MaterialsНеорганические материалы0002-337X3034-5588The Russian Academy of Sciences23188310.31857/S0002337X23070114QGGRDJArticlesСтатьиUnknownMethanol Steam Reforming on Metal–Carbon Catalysts Having Different Carbon SupportsИсследование парового риформинга метанола на металл-углеродных катализаторах с различными углеродными носителямиMironovaE. Yu.МироноваЕ. Ю.zhilyaeva@ips.ac.ruPayen-LytkinaA. A.Пайен-ЛыткинаА. А.yaroslav@igic.ras.ruErmilovaM. M.ЕрмиловаМ. М.yaroslav@igic.ras.ruOrekhovaN. V.ОреховаН. В.yaroslav@igic.ras.ruZhilyaevaN. A.ЖиляеваН. А.
Russian Federation
kipnis@ips.ac.ruEfimovM. N.ЕфимовМ. Н.efimov@ips.ac.ruVasilevA. A.ВасильевА. А.efimov@ips.ac.ruSteninaI. A.СтенинаИ. А.stenina@igic.ras.ruYaroslavtsevA. B.ЯрославцевА. Б.zhilyaeva@ips.ac.ruTopchiev Institute of Petrochemical Synthesis, Russian Academy of SciencesИнститут нефтехимического синтеза им. А.В. Топчиева РАНTopchiev Institute of Petrochemical Synthesis, Russian Academy of SciencesИнститут нефтехимического синтеза им. А.В. Топчиева Российской академии наукTopchiev Institute of Petrochemical Synthesis, Russian Academy of SciencesФГБУН Институт нефтехимического синтеза им. А. В. Топчиева РАНKurnakov Institute of General and Inorganic Chemistry, Russian Academy of SciencesИнститут общей и неорганической химии им. Н.С. Курнакова РАН0107202359775976525122023Copyright ©; 2023, Е.Ю. Миронова, А.А. Пайен-Лыткина, М.М. Ермилова, Н.В. Орехова, Н.А. Жиляева, М.Н. Ефимов, А.А. Васильев, И.А. Стенина, А.Б. ЯрославцевCopyright ©; 2023, Е.Ю. Миронова, А.А. Пайен-Лыткина, М.М. Ермилова, Н.В. Орехова, Н.А. Жиляева, М.Н. Ефимов, А.А. Васильев, И.А. Стенина, А.Б. Ярославцев2023Е.Ю. Миронова, А.А. Пайен-Лыткина, М.М. Ермилова, Н.В. Орехова, Н.А. Жиляева, М.Н. Ефимов, А.А. Васильев, И.А. Стенина, А.Б. ЯрославцевЕ.Ю. Миронова, А.А. Пайен-Лыткина, М.М. Ермилова, Н.В. Орехова, Н.А. Жиляева, М.Н. Ефимов, А.А. Васильев, И.А. Стенина, А.Б. Ярославцевhttps://journals.rcsi.science/0002-337X/article/view/231883

We have studied Cu–Zn and Cu–Ni containing catalysts on carbon supports based on IR-pyrolyzed chitosan and detonation nanodiamond (DND) and assessed their activity for the methanol steam reforming process. All of the catalysts have demonstrated rather high activity for this process and good stability over 30 h of continuous operation. The DND-based catalysts have been shown to have better performance, which seems to be due to their larger surface area and the nature of the functional groups on their surface. The activity of the bimetallic catalysts and the nature of the supports have been shown to be interrelated.

Изучены катализаторы на углеродных носителях на основе ИК-пиролизованного хитозана и детонационных наноалмазов (ДНА), содержащие Cu и Zn или Ni, в процессе паровой конверсии метанола. Все исследованные образцы показали достаточно высокую активность в данном процессе и стабильность в течение 30 ч непрерывной работы. Показано преимущество катализаторов на основе ДНА, причиной чего, видимо, является их более развитая поверхность и природа присутствующих на ней функциональных групп. Показана взаимосвязь между активностью биметаллических катализаторов и природой носителя.

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